环氧树脂属于热塑性的线型树脂,不能直接应用,必须向其中添加固化剂组分,生成三维网络结构才能体现其独特的性能。在固化剂产品中,酸酐类固化剂占有重要地位,是固化剂市场用量较大,应用较为广泛的品种之一。
Epoxy resin is a kind of thermoplastic linear resin, which can not be directly used. It is necessary to add curing agent components to it to form a three-dimensional network structure to reflect its unique performance. Among the curing agent products, the anhydride curing agent plays an important role. It is one of the widely used curing agent products with large market consumption.
环氧树脂和酸酐类固化剂及其他添加剂(如促进剂、增韧剂、填料、偶联剂、颜料等经过加热,通过各种加工工艺,形成不同形态的热固性加成物。酸酐体系固化剂的特点是收缩率小、没有副产物,耐热性好,密封性佳,绝缘性好,各种助剂选择性大。可应用在电子灌封、电器浇注、包封、拉挤、缠绕、层压绝缘材料及复合材料、粉末涂料等领域。
Epoxy resin, anhydride curing agent and other additives (such as accelerant, toughening agent, filler, coupling agent, pigment, etc.) are heated to form different forms of thermosetting adducts through various processing technologies. The curing agent of anhydrides system is characterized by small shrinkage, no by-products, good heat resistance, good sealing, good insulation and high selectivity of various additives. It can be used in electronic potting, electrical pouring, encapsulation, pultrusion, winding, laminated insulating materials and composite materials, powder coating and other fields.
1、 电子灌封
1. Electronic potting
电子灌封产品从小型电子元件、精密仪表、军工通讯产品,及各种电子浇注制品大型变压器,从电机线圈到高压电器中电流互感器、电缆接线盒和电缆终端等,酸酐类固化剂得到广泛应用。
Electronic potting products from small electronic components, precision instruments, military communication products, and a variety of electronic casting products large transformers, from motor coils to high-voltage electrical current transformers, cable junction boxes and cable terminals, etc., anhydride curing agent has been widely used.
2、 拉挤产品
2. Pultrusion products
拉挤成型时将浸渍树脂胶液的连续玻璃纤维束、带或布等,在牵引力的作用下,连续不断地生产长度不限的玻璃钢型材。这种工艺适合生产各种断面形状的玻璃钢型材,如棒,管,工字形、槽形、方形型材和空腹型材等。
During pultrusion, continuous fiberglass bundles, belts or cloth impregnated with resin glue are continuously produced with unlimited length fiberglass profiles under the action of traction. This process is suitable for producing FRP profiles with various cross-section shapes, such as bar, tube, I-shape, groove, square profile and hollow profile.
拉挤制品生产中,环氧树脂体系固化剂一般采用酸酐类固化剂。尽管也采用不饱和树脂拉挤成型加工,但其综合性能,尤其在机械性能、绝缘性能、收缩率方面,均不如环氧树脂拉挤产品。
In the production of pultrusion products, the curing agent of epoxy resin system is generally anhydrides. Although it is also processed by pultrusion of unsaturated resin, its comprehensive properties, especially in mechanical properties, insulation properties and shrinkage, are not as good as epoxy pultrusion products.
3、 层压产品
3. Laminated products
环氧层压制品是由纤维织物增强材料浸渍环氧树脂/固化剂等配制成的胶液,经一定温度烘干得到半固化片,半固化片经裁切、叠层,而后热压固化成板材,经卷绕加热固化成管材和筒材。
The epoxy laminated product is a kind of glue liquid which is made up of fiber fabric reinforced material impregnated with epoxy resin / curing agent. After drying at a certain temperature, the semi-cured sheet is obtained. The semi-cured sheet is cut and laminated, then hot pressed and solidified into plate, and then heated and solidified into tube and tube.
层压产品使用环氧树脂体系中,主要使用酸酐类固化剂,胺类固化剂使用双氰胺及芳香胺,也有采用合成树脂作固化剂。
In the epoxy resin system, the main curing agent for laminating products is anhydrides, dicyandiamide and aromatic amine are used as amine curing agents, and synthetic resin is also used as curing agent.
环氧覆铜箔层压板是电子工业的基础材料,用于制造印刷线路板,广泛应用于电子计算机、通讯设备、仪表设备、家用电器等。
Epoxy copper-clad laminate is the basic material of electronic industry, which is used to manufacture printed circuit board and widely used in electronic computer, communication equipment, instrument equipment, household appliances, etc.
4、 缠绕制品
4. Winding products
缠绕制品是将浸过树脂的连续纤维(布、予浸纱)按照一定规律缠绕到芯模上,然后经过固化、脱模而获得一定形状制品。
Winding products are made by winding resin impregnated continuous fibers (cloth, pre impregnated yarn) onto the core mould according to certain rules, and then solidify and demould to obtain certain shape products.
缠绕制品更具代表性的是使用期长、粘度小、发热量少、毒性小的环氧固化体系,故一般都选用液体酸酐为主。
The most representative of winding products is the epoxy curing system with long service life, small viscosity, less heat and less toxicity, so liquid anhydrides are generally selected as the main component.
5、 模塑料制品
5. Molded plastic products
模塑料主要是对小型电子元件如晶体管、集成电路、电容器、电阻器等进行包封。它的优点是操作方便,生产效率高,可以采用较多填料。它使用的固化剂既有酸酐固化剂也有胺类固化剂。
Mold plastic is mainly used to pack small electronic components such as transistors, integrated circuits, capacitors, resistors, etc. It has the advantages of convenient operation, high production efficiency, and can use more fillers. The curing agent used in the utility model includes both an anhydride curing agent and an amine curing agent.
6、 真空压力浸胶制品
6. Vacuum pressure impregnated products
在真空压力浸胶制品工艺生产中,先将玻璃布卷绕在管芯轴上,装入模具内,然后在真空下将环氧胶黏剂吸入模腔内,再在一定压力和温度下进行凝胶固化便可获得管材。
In the production process of vacuum pressure dipping products, first, the glass cloth is wound on the shaft of the tube and loaded into the mold, then the epoxy adhesive is sucked into the mold cavity under vacuum, and then the gel is solidified at a certain pressure and temperature to obtain the tube.
该生产工艺主要采用液体酸酐类固化剂。
The production process mainly uses liquid anhydrides curing agent.
7、 环氧树脂涂料
7. Epoxy resin coating
环氧树脂在涂料工艺中主要利用它优良的粘接性以及优异的耐化学品性能,它在防腐蚀、电气绝缘、交通运输、土木建筑等领域有着广泛应用。
Epoxy resin is mainly used in coating process for its excellent adhesiveness and chemical resistance. It is widely used in anti-corrosion, electrical insulation, transportation, civil construction and other fields.
环氧树脂涂料中应用酸酐类固化剂的主要有滴浸漆、粉云母带粘合绝缘漆、粉末涂料等。
The main curing agents used in epoxy resin coating are dip coating, mica tape adhesive insulating coating, powder coating, etc.
酸酐类固化剂中,液体酸酐类因其便利的操作工艺,超高的性价比,在市场上应用更为广泛。
Among the anhydrides, liquid anhydrides are widely used in the market due to their convenient operation process and high cost performance.