一种回收顺酐的工艺方法。该方法是以正丁醇与含有顺酐生成气进行酯化反应生成单酯，再将单酯分解成正丁醇和顺酐。该工艺的特征在于设置一个热分解反应精馏塔，它以酯化反应生成的单酯和一定含量的二酯为原料，在相应的工况下在塔内进行反应蒸馏，塔顶产出正丁醇回酯化反应塔循环使用，塔底产出顺酐和二酯去精品精馏塔进行顺酐精制。具有吸收快、吸收收率高、不腐蚀设备、无三废、、操作可靠特点。
The invention relates to a process for recovering maleic anhydride. In this method, n-butanol is esterified with the gas containing maleic anhydride to produce a monoester, and then the monoester is decomposed into n-butanol and maleic anhydride. The process is characterized in that a thermal decomposition reactive distillation column is set, which takes the monoester and a certain amount of diester generated by esterification reaction as raw materials, carries out reactive distillation in the column under corresponding working conditions, the n-butanol produced at the top of the column is recycled to the esterification reaction column, and the maleic anhydride and diester produced at the bottom of the column are sent to the fine distillation column for maleic anhydride refining. It has the characteristics of fast absorption, high absorption yield, no corrosion of equipment, no three wastes, energy saving and reliable operation.
正丁醇在室温无催化剂条件下，与含有顺酐反应生成气反应生成单酯（ＭＢＭ），再将单酯加热反应，生成正丁醇和顺酐的工艺路线回收顺酐的新工艺，它由酯化反应吸收塔１，正丁醇予处理塔２和冷凝器５，冷却器６，及精品精馏塔４和冷却器８所构成，其特征在于，设置一个热分解反应精馏塔３及塔顶冷凝器７，该塔以酯化反应吸收塔塔底产出的单酯和一定量的二酯为原料。
Under the condition of no catalyst at room temperature, n-butanol reacts with the gas containing maleic anhydride to produce monoester (MBM), and then the monoester is heated and reacted to produce n-butanol and maleic anhydride. It is a new process for recovering maleic anhydride. It is composed of esterification reaction absorber 1, n-butanol pretreatment tower 2, condenser 5, cooler 6, fine distillation tower 4 and cooler 8, The utility model is characterized in that a thermal decomposition reaction distillation tower 3 and a tower top condenser 7 are set, which takes the monoester and a certain amount of diester produced at the bottom of the esterification reaction absorption tower as raw materials.
在进料温度为５０℃－１２０℃，塔顶真空度为３００－７５０ｍｍＨｇ，回流比为１－３的工况下实行热分解反应精馏，塔顶产出纯正丁醇经冷凝器７送回酯化反应吸收塔１循环使用，塔底产出顺酐与二酯送精品精馏塔４进行顺酐精制。
Under the conditions that the feed temperature is 50 ℃ - 120 ℃, the vacuum degree at the top of the tower is 300-750mmhg and the reflux ratio is 1-3, the thermal decomposition reactive distillation is implemented. The pure butanol produced at the top of the tower is sent back to the esterification reaction absorber 1 for recycling through the condenser 7. The maleic anhydride and diester produced at the bottom of the tower are sent to the fine distillation tower 4 for maleic anhydride refining.
